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The Radical Pair Mechanism and the Avian Chemical Compass: Quantum Coherence and Entanglement

机译:激进对机制和禽类化学指南针:量子   连贯与纠缠

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摘要

We review the spin radical pair mechanism which is a promising explanation ofavian navigation. This mechanism is based on the dependence of product yieldson (1) the hyperfine interaction involving electron spins and neighboringnuclear spins and (2) the intensity and orientation of the geomagnetic field.One surprising result is that even at ambient conditions quantum entanglementof electron spins can play an important role in avian magnetoreception. Thisreview describes the general scheme of chemical reactions involving radicalpairs generated from singlet and triplet precursors; the spin dynamics of theradical pairs; and the magnetic field dependence of product yields caused bythe radical pair mechanism. The main part of the review includes a descriptionof the chemical compass in birds. We review: the general properties of theavian compass; the basic scheme of the radical pair mechanism; the reactionkinetics in cryptochrome; quantum coherence and entanglement in the aviancompass; and the effects of noise. We believe that the "quantum avian compass"can play an important role in avian navigation and can also provide thefoundation for a new generation of sensitive and selective magnetic-sensingnano-devices.
机译:我们审查了自旋自由基对机制,这是鸟类导航的有希望的解释。这种机理是基于产物屈服系数(1)与电子自旋和邻近核自旋的超精细相互作用以及(2)地磁场的强度和方向的依赖性而得出的。一个令人惊讶的结果是,即使在环境条件下,电子自旋的量子纠缠也可以发挥作用。在禽磁感受中起重要作用。这篇综述描述了涉及由单重态和三重态前体产生的自由基对的化学反应的一般方案;自由基对的自旋动力学;自由基对机理引起的产物产率的磁场依赖性。审查的主要部分包括对鸟类化学罗盘的描述。我们来回顾一下:theavian罗盘的一般特性;自由基对机制的基本方案;隐色染料的反应动力学;鸟指南针中的量子相干和纠缠;和噪音的影响。我们认为,“量子禽类罗盘”可以在禽类导航中发挥重要作用,也可以为新一代灵敏,选择性的磁感应纳米设备提供基础。

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